The first example of trimethylsilyl methylenenitronate reacting with aldehydes under an apparent Mukaiyama nitro-aldol reaction

dc.contributor.author	Pottie, Ian
dc.contributor.author	MacDonald, Frank
dc.contributor.author	Carneiroa, Karina
dc.date.accessioned	2014-10-30T15:25:04Z
dc.date.available	2014-10-30T15:25:04Z
dc.date.issued	2011-02-08
dc.description.abstract	Trimethylsilyl methylenenitronate reacts with both aliphatic and aromatic aldehydes in the presence of catalytic amounts of scandium(III) triflate to form the Henry reaction products in low (25%) to good yields (77%). This is the first example of this silyl nitronate undergoing a nitro-aldol reaction under an acid environment.	en_US
dc.format.availability	Full-text	en_US
dc.identifier.citation	MacDonald, F. K., Carneiro, K. M. M., & Pottie, I. R. (2011). The first example of trimethylsilyl methylenenitronate reacting with aldehydes under an apparent Mukaiyama nitro-aldol reaction. Tetrahedron Letters, 52(8), 891–893. doi:10.1016/j.tetlet.2010.12.056	en_US
dc.identifier.other	10.1016/j.tetlet.2010.12.056
dc.identifier.uri	https://hdl.handle.net/10587/1419
dc.language.iso	en	en_US
dc.publisher	Tetrahedron Letters	en_US
dc.subject	Mukaiyama nitro-aldol	en_US
dc.subject	1,2-Nitroalcohol	en_US
dc.subject	Henry reaction	en_US
dc.subject	Silyl nitronate	en_US
dc.subject	Scandium triflate	en_US
dc.title	The first example of trimethylsilyl methylenenitronate reacting with aldehydes under an apparent Mukaiyama nitro-aldol reaction	en_US
dc.type	Article	en_US